The document chemical process simulation and the aspen hysys software, version 7. Press the down arrow key to move to the input cell for methane. Due to a high temperature flue gas flowing out of the radiant box of such a reformer, the proper design of the waste heat recovery modules requires a complex procedure and is. In this paper, the industrial secondary reformer reactor has been modeled and simulated at steadystate operation conditions. It is define the fluid package by choosing the pengrobinson equation of state and equilibrium. Steam naphtha reformer material balance posted in refining, hydrocarbons, oil, and gas. A process flow diagram of the simulation done in hysys is presented in figure 3. Steam reforming the basics of reforming, shapes and carbon. Steam methane reforming syngas production air liquide. From the three combustion reactions shown above, reaction. Heat and power integration of methane reforming based hydrogen. In the steammethane reforming reaction, 3 molecules of hydrogen are being produced. Additional information on hysys thermodynamics packages can be found in the simulation basis manual appendix a. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr.
In hysys there is a limited online help package, which can be obtained using the help command from the menu bar or by pressing the f1 key. During the steam methane reforming smr reaction, methane reacts with steam to form syngas, i. Hydrogen from natural gas via steam methane reforming smr. Methane reforming smr most common method of manufacturing hydrogen 90 95 vol% typical purity gasification partial oxidation. Kinetics of methane steam reforming over a commercial nickelbased catalyst and over an innovative rhodiumperovskite catalyst of formula barh x zr 1. Co are also active for the methane steam reforming 25. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. Natural gas reformation chemical engineering innovations. This syngas is further decomposed to ammonia, h2, liquid fuels, and methanol.
Reforming, catalytic cracking, hydrocracking hydrocracking severe form of hydroprocessing break carbon. Kinetics, catalysis and mechanism of methane steam reforming. Reformancesmr catalysts for steam methane reforming to. The reforming reactions to produce hydrogen are endothermic, and the reaction requires a high temperature to proceed under equilibrium conditions. Open a new case by clicking on the blank white page or use the commands file new. You can easily model the steammethane reformer smr using the hysys software or aspenplus from apsen technologies corporation. Aspen hysys 2006 provides tool to design a steady and dynamics state. Steam methane reforming is the most common and economical way to make hydrogen. Pdf comparative simulation of a fluidised bed reformer. Steps of designging a steam methane reformer for syngas production.
The secondary reformer is a part of a subprocess in a higher scale unit of ammonia synthesis. The simulation procedure of the reforming of natural gas is presented as following. The steam methane reforming process can be broken down into five distinct steps. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Given the intrinsic kinetics, the tortuosity factor of a nimgal 2 o 4 catalyst was determined under reaction conditions by minimizing the sum of squares of residuals of the exper. Steam methane reforming simulation hydrogen production hysys. Simulating the production of propylene glycol from water and propylene oxide using hysys duration. Carbon monoxide is reacted downstream in two, high and lowtemperature. The reaction is strongly endothermic consumes heat.
Simulation of methane slippage in steam methane reforming mohd. Natural gas, acid gas to syngas, low emissions, syngas, steam reforming. In recent years, hydrogen h 2 has gained much research emphasis as an energy carrier due to its environmental friendliness and wide range of energy applications. The pengrobinson equations of state were used to calculate the stream physical and transport properties.
If anyone is working with modelling of steam methane reforming with. The carbon steam ratio is critical in methane reforming processes and should be maintained above the minimum specified for the reformer. Pdf kinetic based simulation of methane steam reforming. Fbcr was used for detailed modelling of the catalyst beds considering rigorous intraparticle mass and heat transport. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. Get your team aligned with all the tools you need on one secure, reliable video platform. Process analysis of solar steam reforming of methane for producing. Modeling and simulation of an industrial secondary. Hysys tutorials and applications pdf free download. In hysys simulation it is added a new component list which contain methane, water, carbon monoxide, carbon dioxide, hydrogen, nitrogen and oxygen as components. Onsite hydrogen generation by steam methane reforming.
Change the composition basis to mass fractions by selecting the appropriate radio button, or by pressing alt n. The steam reforming of methane srm is a fieldproven technology for. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Smr is a costeffective and energy efficient way of producing hydrogen. Carbon deposition in methane reformer chemical plant. Mitigating carbon dioxide impact of industrial steam methane. Figures 2 and 3 show examples of curves of total methane conversion and of conversion of methane into c02 vs. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Simulation of hydrogen production for mobile fuel cell. This study focuses on process intensification of the hydrocarbon reforming process, particularly methane reforming, because this process is essential to the production of many chemicals such as methanol and ammonia, but emits a large amount of co 2. Evaluated current public programs available to reduce the cost of biomass as a feedstock.
Using hysys, you can model and simulate the steam ethane reforming with propylene very easy. Performed an economic analysis of the production of hydrogen from the three biomass feedstocks. To reduce pressure drop during the process, traditional smr catalysts such as nial2o3 promoted with mgo andor cao are formed in the. Syngas production the global syngas technologies council. Steam reforming of methane steam reforming of methaneitso chen october 24, 2010submitted as coursework for physics 240, stanford university, fall 2010. Under these conditions, the catalyst presents the average h2co.
Integration of methane steam reforming and water gas shift. Methane steam reforming reaction behaviour in a packed. A simulation model is developed by commercial simulators in order to predict the performance of a fluidised bed reformer. Methane steam reforming msr is a wellestablished production method that currently generates 95% of hydrogen in the u. Hi all, i want to calculate material balance for naphtha steam reformer. Water enters the furnace, producing steam at a very high temperature. Advanced modelling and optimisation of natural gas. Methane steam reforming is a wellestablished process as shown in fig. Please guide me with the techniques used and references available. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. A mixture of methane and steam convert to hydrogen and carbondioxide. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Kinetic of methane steam reforming reaction over nickel. The much lower cost of natural gas and the desire to reduce carbon dioxide emissions have stimulated interest in the dry methane reforming process in which these two gases react to produce synthesis gas.
Steam methane reforming simulation hydrogen production hysys tutorial p sims. Supplemental material for elementary principles of chemical processes. Recovery of co 2 from units of steam methane reforming at. Parametric studies for key operating conditions like a h 2 permeance, a h 2 o sweep gas flow rate, operating temperature, and a co 2 ch 4 ratio were carried out for a conventional packedbed reactor pbr and a mr using aspen hysys, a. Concentrating solar power library, user manual, graz, 2016, search pubmed. This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Stabilize steam methane reformer combustion, reduce variability, and gain control of energy costs with emersons steam methane reformer solution, which will enable your operators to respond to changing conditions, keep your equipment from degrading and failing, and. Experiential learning and working with students in the labs 6. Methane steam reforming, methanation and watergas shift. Inside a proprietary topfired steam reformer, the feed gas and steam are then heated at pressures of 15 45 barg to generate hydrogen, carbon monoxide and carbon dioxide.
Technoeconomic analysis tea for co 2 reforming of methane in a membrane reactor mr was conducted by using process simulation and economic analysis. The main purpose of this technology is hydrogen production. The ratio of hydrogen to carbon monoxide in the resulting synthesis gas is close to unity, which makes it suitable for feeding to the fischertropsch process to produce liquid transportation. Design and control of the dry methane reforming process. Mass and energy balances have been established for all cases. As many physical and chemical phenomena take place in the reformer, two.
A conventional methane reforming based hydrogen production plant. Since these compounds are hydrocarbons, use the pengrobinson thermodynamic package. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. Steam methane reforming simulation hydrogen production hysys tutorial. Cost and performance comparison of stationary hydrogen. What is the best aspen plus model for simulation of steam. Steam methane reforming simulation hydrogen production. Steam methane reforming chemical process simulation. Overview of the book learn aspen plus in 24 hours 3. Extensive experimental runs were firstly carried out in a microreactor, with the catalysts in powder form, to evaluate their performances in steam methane. Not only methane is used in steamreforming processes.
Process assessments for lowtemperature methane reforming. Fuels, such as ethanol, propane, and gasoline, are utilized to their fullest extent to produce massive amounts of hydrogen. The hfa is composed of a reforming system including the reformer, gas cleanup system, and peripheral components, a hydrogen compressor, storage tanks, and dispenser. Kinetic based simulation of methane steam reforming and water gas shift for hydrogen production using aspen plus article pdf available in chemical engineering transactions 56. Steam methane reforming, or smr, processes feedstocks, ranging from natural gas to light naphtha, mixed with steam to produce a hydrogen rich syngas effluent, with a typical h 2 co ratio of 3. Click on the compositional cell for nitrogen, type 6 for the number of parts of this component, then press enter. Steam methane reforming hydrogen production air liquide. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and another syngas product. For the baseline hfa, we compared the costs and efficiencies of two hydrogengeneration technologies steam methane reforming and autothermal reforming and two hydrogen purification. It is located after the primary reformer in the ammonia plant where it is used in the. Here are several of them illustrated below, along with the watergas shift reaction. It aims to modify a complete mathematical model of the secondary reformer design.373 1280 1140 203 859 1374 1135 151 409 1195 424 1416 487 1212 789 1450 1022 212 1487 162 587 1162 873 348 199 509 1416 368 536